Search for Electric Dipole Moment (EDM)
in Atoms, Molecules, and the Neutron



Introduction
Theoretical Motivation
Detecting an EDM
Experiments
Theoretical Implications Mercury Experiment Data



Introduction

In order for an elementary particle, atom or molecule to possess a permanent electric dipole moment (EDM), time-reversal symmetry must be violated, and through the CPT theorem CP must be violated as well. CP violation was discovered in 1964, but it has been observed only in the decays of the neutral K mesons - and no EDM has yet been found. Experiments to search for an EDM began many decades ago, and are expected to continue with increasing precision well into the future. In the past, EDM experiments played a crucial role in eliminating theories put forward to explain the K tex2html_wrap_inline129 system, because the theories usually predicted too large a dipole moment. The currently accepted Standard Model of Particle Physics predicts unobservably small dipole moments. Therefore, EDM experiments are an ideal probe for new physics beyond the Standard Model, such as supersymmetry, in which the natural size of EDMs of neutrons, atoms and molecules lies within a detectable range.

Theoretical Motivation

CKM Matrix | B factory | Supersymmetry | Strong CP Problem | Baryogenesis

In a general field theory, CP violation is caused by the presence of a complex phase between different fundamental fields. Thus CP violation in the Ktex2html_wrap_inline129 system is accommodated within the Standard Model by allowing some elements of the Cabibbo-Kobayashi-Maskawa (CKM) matrix to be complex. For three generations of quarks exactly one complex phase is allowed, which turns out to have a value of order unity, tex2html_wrap_inline133. The phase cannot be determined more accurately from measurements on the K system because of the hadronic uncertainties.

Although the CP violation is explained naturally by the CKM matrix, it is not possible at present to check the self-consistency of this explanation. To address this problem, the B factory is being build at SLAC to study CP violation in the neutral B meson system. Many different decay modes of the B mesons can be studied, and it will be possible to measure asymmetries in which the hadronic effects cancel. Enough measurements can be performed to over-constrain the elements of the CKM matrix and thus check the consistency of this explanation. The B decays will also allow one to test for other sources of the CP violation. First data from the B factory are expected around the year 2000.

Any extension of the Standard Model which introduces additional particles also allows for additional physically observable phases. The general classes of models that have been considered are supersymmetric models, left-right symmetric models, and multi-Higgs models. At present, the limits on the EDM from measurements in paramagnetic atoms, diamagnetic atoms and the neutron all place comparable constraints on the models, and these constraints are already becoming significant. For example, if supersymmetry were broken near the electroweak scale it would solve the gauge hierachy problem, but then it would also very naturally generate EDMs close to currently observable sizes.

The role of CP symmetry in the theory of strong interactions is also not well understood. The QCD Lagrangian naturally contains a term which violates CP, parameterized by tex2html_wrap_inline135. The limits on neutron and tex2html_wrap_inline137Hg EDM put a limit on tex2html_wrap_inline139, while the natural value of tex2html_wrap_inline135 is of order unity. Several mechanisms have been proposed to explain the smallness of tex2html_wrap_inline135. One of the most popular, Peccei-Quinn symmetry, predicts the existence of an additional pseudoscalar particle, the axion. Many searches for the axion have been conducted with negative results.

Some evidence for CP violation beyond the Standard Model comes from Cosmology. Astronomical observations indicate that our Universe is mostly made of matter and contains almost no anti-matter. In the Big Bang cosmology this asymmetry has to be generated dynamically during cooling of the universe, a process called baryogenesis. CP violation is one of the requirements for baryogenesis. One of the most attractive scenarios of baryogenesis involves the electroweek phase transition at the energy scale of 100 GeV. Because the interactions at this energy scale are well known, one can make relatively reliable estimates of the baryon asymmetry. These estimates indicate that if the only source of CP violation is in the CKM matrix, the baryon asymmetry is smaller than the observed value by many orders of magnitude. However, extensions of the Standard Model, such as supersymmetry or multi-Higgs theories, which involve additional sources of CP violation, can naturally produce the baryon asymmetry of the correct magnitude.

Detecting an EDM


EDM violates time reversal symmetry. By the CPT theorem, it also violates CP (charge and parity) symmetry.





The interaction of the electric dipole moment with the electric field is similar to the interaction of the magnetic dipole moment with the magnetic field.





Under time reversal the direction of the spin changes, since it is an axial vector, while the charge distribution does not change. The electric dipole moment, which is a vector, has to be parallel to the spin, since it is the only available vector in the rest frame of the particle. Therefore, if time reversal is a good symmetry, the electric dipole moment must be zero.


One measures the Larmor precession frequency of the spins in parallel electric and magnetic fields and alternates the relative orientation of the two fields.





Initial field orientation

Final field orientation

The change in frequency is proportional to the electric dipole moment and the applied electric field.









Experiments

Recent Experiments | Future Experiments

A particle with electric and magnetic dipole moments d and tex2html_wrap_inline147 interacts with external electric and magnetic fields tex2html_wrap_inline149 and tex2html_wrap_inline151 by the following Hamiltonian
displaymath153
where tex2html_wrap_inline155 is the total angular momentum. The violation of T is evident when we note that tex2html_wrap_inline149 does not change sign under tex2html_wrap_inline159, whereas tex2html_wrap_inline151 and tex2html_wrap_inline155 both do. In all experiments, the search for an EDM consists of measuring the precession frequency of the particle in parallel electric and magnetic fields and looking for a change of this frequency when the direction oftex2html_wrap_inline149 is reversed relative to tex2html_wrap_inline151.

EDM measurements are carried out either on a beam of the atoms or molecules or on a sample of them held in a bottle. Beams are the method of choice for such atoms and molecules as Tl and TlF which undergo rapid spin relaxation in a bottle. Bottles are usually chosen for those systems which have a long spin relaxation time, tex2html_wrap_inline169, such as Cs, Xe, Hg, or the neutron. The long tex2html_wrap_inline169 obtainable in a bottle means a sharp resonance line and high precision. The bottle also has the advantage of averaging the tex2html_wrap_inline173 motional magnetic field nearly to zero. However, bottles cannot support as large an electric field as beams, and bottles usually have larger high voltage leakage currents.
 

Recent EDM Experiments
Location 
System 
Method 
Latest Result 
Ref. 
Nuclear Spin 
Grenoble, France 
neutron 
Bottle 
tex2html_wrap_inline175e cm 
Gatchina, Russia
neutron 
Bottle 
tex2html_wrap_inline177e cm 
Washington 
tex2html_wrap_inline137Hg
Bottle 
tex2html_wrap_inline181e cm 
Yale 
TlF 
Beam 
tex2html_wrap_inline183e cm 
Electron Spin 
Berkeley 
tex2html_wrap_inline185Tl
Beam 
tex2html_wrap_inline187e cm
Amherst 
tex2html_wrap_inline189Cs
Bottle 
tex2html_wrap_inline191 e cm

[1] K.F. Smith et al., Phys. Lett. B 234, 191 (1990).
[2] I.S. Altarev et al., Phys. Lett. B 276, 242 (1992).
[3] J.P. Jacobs, W.M. Klipstein, S.K. Lamoreaux, B.R. Heckel, and E.N. Fortson, Phys. Rev. A 52, 3521 (1995).
[4] D. Cho, K. Sangster, and E.A. Hinds, Phys. Rev. Lett. 63, 2559 (1989).
[5] E.D. Commins, S.B. Ross, D. DeMille, and B.C. Regan, Phys. Rev. A 50, 2960 (1994).
[6] S.A. Murthy, D. Krause, Z. L. Li, and L.R. Hunter, Phys. Rev. Lett. 63, 965 (1989).

There are extensions of the above experiments, either now underway or expected to begin shortly, that aim to significantly improve the sensitivity to EDM. These include the Berkeley atomic beam experiment that will compare Tl and Na atoms, a cryogenic neutron EDM measurement proposed at LANL, our mercury experiment using a frequency-quadrupled laser diode for optical pumping and a YbF experiment at Sussex. There are also efforts underway at Austin, Stanford and here to apply the techniques of atom cooling and trapping to EDM experiments, as well as a 129Xe-3He spin maser experiement being developed at University of Michigan and Harvard - Smithsonian.

Theoretical Implications

There is a number of ways that CP and T violating interactions between elementary particles could give rise to an atomic (or molecular) EDM; all are enhanced considerably in heavy atoms. Calculations have been made of the atomic EDM due to an EDM distribution in the nucleus, to a T-violating force between electrons and nucleons, and to an intrinsic EDM of the electron itself, corresponding respectively to hadronic (quark-quark), semi-leptonic (electron-quark), and purely leptonic interactions as the chief source of T violation. Generally, purely hadronic interactions are tested most sensitively by the nuclear-spin experiments (the neutron, Hg, and TlF), purely leptonic interactions by the electron-spin experiments (Tl and Cs), and semi-leptonic interactions, in one form or another, by all the atomic and molecular experiments.

The table below gives limits on some of the CP violating parameters set by our measurement in tex2html_wrap_inline137Hg (J.P. Jacobs, W.M. Klipstein, S.K. Lamoreaux, B.R. Heckel, and E.N. Fortson, Phys. Rev. A 52, 3521 (1995)) compared with best limits from other work.
 

Upper limits (95% confidence level) on T-violating interactions set by our tex2html_wrap_inline137Hg result (tex2html_wrap_inline181 e cm) compared with the best current limits from other experiments. 
T-Violating Parameters
Limit from tex2html_wrap_inline137Hg
Best Limit from Other Work
Hadronic
Schiff Moment (tex2html_wrap_inline203)
tex2html_wrap_inline203  < tex2html_wrap_inline207fmtex2html_wrap_inline209
tex2html_wrap_inline203tex2html_wrap_inline213fmtex2html_wrap_inline209
TlF [1]
tex2html_wrap_inline217
tex2html_wrap_inline219 <tex2html_wrap_inline221
tex2html_wrap_inline219tex2html_wrap_inline225
TlF [1]
tex2html_wrap_inline227
tex2html_wrap_inline229 <tex2html_wrap_inline231
tex2html_wrap_inline229tex2html_wrap_inline235
neutron [2]
Semileptonic
tex2html_wrap_inline237
tex2html_wrap_inline239tex2html_wrap_inline241
tex2html_wrap_inline239tex2html_wrap_inline245
TlF [1]
tex2html_wrap_inline247
tex2html_wrap_inline249tex2html_wrap_inline251
tex2html_wrap_inline249tex2html_wrap_inline255
Tl [3]
Leptonic
electron (tex2html_wrap_inline257)
tex2html_wrap_inline257tex2html_wrap_inline261cm
tex2html_wrap_inline257tex2html_wrap_inline265cm
Tl [3]
Gauge Model
QCD phase (tex2html_wrap_inline267)
tex2html_wrap_inline267 <tex2html_wrap_inline271
tex2html_wrap_inline267 <tex2html_wrap_inline275
neutron [2]
Supersymmetry (tex2html_wrap_inline277)
tex2html_wrap_inline279 <tex2html_wrap_inline281
tex2html_wrap_inline279 <tex2html_wrap_inline285
neutron [2]
tex2html_wrap_inline287 <tex2html_wrap_inline289
Tl [3]
Multi-Higgs (tex2html_wrap_inline291)
tex2html_wrap_inline291 <tex2html_wrap_inline295
tex2html_wrap_inline291 <tex2html_wrap_inline295
Tl [3]
Left-Right Sym. (tex2html_wrap_inline301)
tex2html_wrap_inline301 <tex2html_wrap_inline305
tex2html_wrap_inline301 <tex2html_wrap_inline309
neutron [2]

[1] D. Cho, K. Sangster, and E. A. Hinds, Phys. Rev. Lett. 63, 2559 (1989).
[2] K. F. Smith, et al., Phys. Lett. B 234, 191 (1990).
[3] E. D. Commins, S. B. Ross, D. DeMille, and B.C. Regan, Phys. Rev. A 50, 2960 (1994)


Mike Romalis and Siobhan Quinn
Aug 1999